I've never actually seen an entire episode of Jools' show. If you've spent any time looking desperately for every clip of your favorite musician playing live then you've certainly stumbled across his show and the great live performances he hosts (and way before getting desperate enough to watch the cell phone snippets, too).
For the 200th episode, he had...like...EVERYONE on the show. Radiohead, Feist, Mary J. Blige and, yep, Cat Power (everyone?)
I'm so in love with her it's stupid. Since the first few clips came out of her nervously playing through the material on "The Greatest," she has toured extensively, been hired by Karl Lagerfield, contributed a track to the "I'm Not There" OST (see my review in the archives) and just recently released her second covers album "Jukebox." The point is: she's done a bit and it shows on this clip! She looks completely at ease and sounds as good as i've ever heard her.